Copper mediated C–H amination with oximes: en route to primary anilines

Here we report an efficient Cu(i)-mediated C–H amination reaction with oximes as amino donors to introduce NH(2) groups directly. Various strongly coordinating heterocycles including quinoline, pyrimidine, pyrazine, pyrazole and triazole were tolerated well. The potential utility was further demonst...

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Detalles Bibliográficos
Autores principales: Xu, Lin-Lin, Wang, Xing, Ma, Biao, Yin, Ming-Xing, Lin, Hai-Xia, Dai, Hui-Xiong, Yu, Jin-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001278/
https://www.ncbi.nlm.nih.gov/pubmed/29997868
http://dx.doi.org/10.1039/c8sc01256c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001278/
https://www.ncbi.nlm.nih.gov/pubmed/29997868
http://dx.doi.org/10.1039/c8sc01256c

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