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Carboxylate-directed C–H allylation with allyl alcohols or ethers

A [Ru(p-cymene)Cl(2)](2) catalyst activates allyl alcohols and ethers for the regioselective ortho-C–H allylation of aromatic and heteroaromatic carboxylates. The reaction is orthogonal to most C–H functionalisations with allyl alcohols in that allyl arenes rather than carbonyl compounds are obtaine...

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Detalles Bibliográficos
Autores principales: Hu, Xiao-Qiang, Hu, Zhiyong, Trita, A. Stefania, Zhang, Guodong, Gooßen, Lukas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001406/
https://www.ncbi.nlm.nih.gov/pubmed/29997885
http://dx.doi.org/10.1039/c8sc01741g