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Heterolytic Si−H Bond Cleavage at a Molybdenum‐Oxido‐Based Lewis Pair
The reaction of a molybdenum(VI) oxido imido complex with the strong Lewis acid B(C(6)F(5))(3) gave access to the Lewis adduct [Mo{OB(C(6)F(5))(3)}(NtBu)L(2)] featuring reversible B−O bonding in solution. The resulting frustrated Lewis pair (FLP)‐like reactivity is reflected by the compound's a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001527/ https://www.ncbi.nlm.nih.gov/pubmed/29521459 http://dx.doi.org/10.1002/chem.201800226 |