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Heterolytic Si−H Bond Cleavage at a Molybdenum‐Oxido‐Based Lewis Pair

The reaction of a molybdenum(VI) oxido imido complex with the strong Lewis acid B(C(6)F(5))(3) gave access to the Lewis adduct [Mo{OB(C(6)F(5))(3)}(NtBu)L(2)] featuring reversible B−O bonding in solution. The resulting frustrated Lewis pair (FLP)‐like reactivity is reflected by the compound's a...

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Detalles Bibliográficos
Autores principales:	Zwettler, Niklas, Walg, Simon P., Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001527/ https://www.ncbi.nlm.nih.gov/pubmed/29521459 http://dx.doi.org/10.1002/chem.201800226

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