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Chemical Glucosylation of Labile Natural Products Using a (2‐Nitrophenyl)acetyl‐Protected Glucosyl Acetimidate Donor

The synthesis of (2‐nitrophenyl)acetyl (NPAc)‐protected glucosyl donors is described that were designed for the neighboring‐group assisted glucosylation of base‐labile natural products also being sensitive to hydrogenolysis. Glycosylation conditions were optimized using a trichloroacetimidate glucos...

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Detalles Bibliográficos
Autores principales: Weber, Julia, Schwarz, Markus, Schiefer, Andrea, Hametner, Christian, Häubl, Georg, Fröhlich, Johannes, Mikula, Hannes
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001546/
https://www.ncbi.nlm.nih.gov/pubmed/29937688
http://dx.doi.org/10.1002/ejoc.201800260