Sc(3)N@I(h)-C(80) as a novel Lewis acid to trap abnormal N-heterocyclic carbenes: the unprecedented formation of a singly bonded [6,6,6]-adduct

The reaction between an N-heterocyclic carbene (NHC), namely 1,3-bis(diisopropylphenyl)-imidazol-2-ylene (1), and Sc(3)N@I(h)-C(80) successfully affords a Lewis acid–base pair (2a). Single crystal X-ray crystallographic results unambiguously reveal the unexpected structure of 2a where the abnormal c...

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Detalles Bibliográficos
Autores principales: Chen, Muqing, Bao, Lipiao, Ai, Min, Shen, Wangqiang, Lu, Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6003601/
https://www.ncbi.nlm.nih.gov/pubmed/29997775
http://dx.doi.org/10.1039/c5sc04070a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6003601/
https://www.ncbi.nlm.nih.gov/pubmed/29997775
http://dx.doi.org/10.1039/c5sc04070a

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