Isolation of Au-, Co-η(1)PCO and Cu-η(2)PCO complexes, conversion of an Ir–η(1)PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion

Sodium phosphaethynolate reacts with [MCl(PDI)] (M = Co, Ir; PDI = pyridinediimine) to give metallaphosphaketenes, which in the case of iridium rearranges into a dimetalladiphosphene, via CO migration from phosphorus to the metal. Two different bonding modes of the PCO anion to CAAC-coinage metal co...

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Detalles Bibliográficos
Autores principales: Liu, Liu, Ruiz, David A., Dahcheh, Fatme, Bertrand, Guy, Suter, Riccardo, Tondreau, Aaron M., Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6003603/
https://www.ncbi.nlm.nih.gov/pubmed/29997776
http://dx.doi.org/10.1039/c5sc04504e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6003603/
https://www.ncbi.nlm.nih.gov/pubmed/29997776
http://dx.doi.org/10.1039/c5sc04504e

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