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Isolation of Au-, Co-η(1)PCO and Cu-η(2)PCO complexes, conversion of an Ir–η(1)PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion
Sodium phosphaethynolate reacts with [MCl(PDI)] (M = Co, Ir; PDI = pyridinediimine) to give metallaphosphaketenes, which in the case of iridium rearranges into a dimetalladiphosphene, via CO migration from phosphorus to the metal. Two different bonding modes of the PCO anion to CAAC-coinage metal co...
Autores principales: | Liu, Liu, Ruiz, David A., Dahcheh, Fatme, Bertrand, Guy, Suter, Riccardo, Tondreau, Aaron M., Grützmacher, Hansjörg |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6003603/ https://www.ncbi.nlm.nih.gov/pubmed/29997776 http://dx.doi.org/10.1039/c5sc04504e |
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