Fluctuating hydrogen-bond networks govern anomalous electron transfer kinetics in a blue copper protein

We combine experimental and computational methods to address the anomalous kinetics of long-range electron transfer (ET) in mutants of Pseudomonas aeruginosa azurin. ET rates and driving forces for wild type (WT) and three N47X mutants (X = L, S, and D) of Ru(2,2′-bipyridine)(2) (imidazole)(His83) a...

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Detalles Bibliográficos
Autores principales: Kretchmer, Joshua S., Boekelheide, Nicholas, Warren, Jeffrey J., Winkler, Jay R., Gray, Harry B., Miller, Thomas F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2018
Materias:
Physical Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6004490/
https://www.ncbi.nlm.nih.gov/pubmed/29844178
http://dx.doi.org/10.1073/pnas.1805719115

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6004490/
https://www.ncbi.nlm.nih.gov/pubmed/29844178
http://dx.doi.org/10.1073/pnas.1805719115

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