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Fluctuating hydrogen-bond networks govern anomalous electron transfer kinetics in a blue copper protein
We combine experimental and computational methods to address the anomalous kinetics of long-range electron transfer (ET) in mutants of Pseudomonas aeruginosa azurin. ET rates and driving forces for wild type (WT) and three N47X mutants (X = L, S, and D) of Ru(2,2′-bipyridine)(2) (imidazole)(His83) a...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
National Academy of Sciences
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6004490/ https://www.ncbi.nlm.nih.gov/pubmed/29844178 http://dx.doi.org/10.1073/pnas.1805719115 |