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Chemoselective nitro reduction and hydroamination using a single iron catalyst

The reduction and reductive addition (formal hydroamination) of functionalised nitroarenes is reported using a simple and bench-stable iron(iii) catalyst and silane. The reduction is chemoselective for nitro groups over an array of reactive functionalities (ketone, ester, amide, nitrile, sulfonyl an...

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Detalles Bibliográficos
Autores principales: Zhu, Kailong, Shaver, Michael P., Thomas, Stephen P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005157/
https://www.ncbi.nlm.nih.gov/pubmed/29997793
http://dx.doi.org/10.1039/c5sc04471e