Direct observation by time-resolved infrared spectroscopy of the bright and the dark excited states of the [Ru(phen)(2)(dppz)](2+) light-switch compound in solution and when bound to DNA

The [Ru(phen)(2)(dppz)](2+) complex (1) is non-emissive in water but is highly luminescent in organic solvents or when bound to DNA, making it a useful probe for DNA binding. To date, a complete mechanistic explanation for this “light-switch” effect is still lacking. With this in mind we have undert...

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Detalles Bibliográficos
Autores principales: Poynton, Fergus E., Hall, James P., Keane, Páraic M., Schwarz, Christine, Sazanovich, Igor V., Towrie, Michael, Gunnlaugsson, Thorfinnur, Cardin, Christine J., Cardin, David J., Quinn, Susan J., Long, Conor, Kelly, John M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005197/
https://www.ncbi.nlm.nih.gov/pubmed/29997799
http://dx.doi.org/10.1039/c5sc04514b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005197/
https://www.ncbi.nlm.nih.gov/pubmed/29997799
http://dx.doi.org/10.1039/c5sc04514b

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