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Direct observation by time-resolved infrared spectroscopy of the bright and the dark excited states of the [Ru(phen)(2)(dppz)](2+) light-switch compound in solution and when bound to DNA
The [Ru(phen)(2)(dppz)](2+) complex (1) is non-emissive in water but is highly luminescent in organic solvents or when bound to DNA, making it a useful probe for DNA binding. To date, a complete mechanistic explanation for this “light-switch” effect is still lacking. With this in mind we have undert...
Autores principales: | Poynton, Fergus E., Hall, James P., Keane, Páraic M., Schwarz, Christine, Sazanovich, Igor V., Towrie, Michael, Gunnlaugsson, Thorfinnur, Cardin, Christine J., Cardin, David J., Quinn, Susan J., Long, Conor, Kelly, John M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005197/ https://www.ncbi.nlm.nih.gov/pubmed/29997799 http://dx.doi.org/10.1039/c5sc04514b |
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