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Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts

Four heterotrinuclear complexes containing the ligands 3,5-bis(2-pyridyl)pyrazolate (bpp(–)) and 2,2′:6′,2′′-terpyridine (trpy) of the general formula {[Ru(II)(trpy)](2)(μ-[M(X)(2)(bpp)(2)])}(PF(6))(2), where M = Co(II), Mn(II) and X = Cl(–), AcO(–) (M = Co(II), X = Cl(–): Ru(2)Co–Cl(2); M = Mn(II),...

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Detalles Bibliográficos
Autores principales: Mognon, Lorenzo, Mandal, Sukanta, Castillo, Carmen E., Fortage, Jérôme, Molton, Florian, Aromí, Guillem, Benet-Buchhlolz, Jordi, Collomb, Marie-Noëlle, Llobet, Antoni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006862/
https://www.ncbi.nlm.nih.gov/pubmed/29997822
http://dx.doi.org/10.1039/c5sc04672f