Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines

A broad range of secondary and tertiary amides has been hydrogenated to the corresponding amines under mild conditions using an in situ catalyst generated by combining [Ru(acac)(3)], 1,1,1-tris(diphenylphosphinomethyl)ethane (Triphos) and Yb(OTf)(3). The presence of the metal triflate allows to miti...

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Detalles Bibliográficos
Autores principales: Cabrero-Antonino, Jose R., Alberico, Elisabetta, Junge, Kathrin, Junge, Henrik, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006866/
https://www.ncbi.nlm.nih.gov/pubmed/29997838
http://dx.doi.org/10.1039/c5sc04671h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006866/
https://www.ncbi.nlm.nih.gov/pubmed/29997838
http://dx.doi.org/10.1039/c5sc04671h

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