Electronic structure and reactivity of nickel(i) pincer complexes: their aerobic transformation to peroxo species and site selective C–H oxygenation

The study is aimed at a deeper understanding of the electronic structure of the T-shaped nickel(i) complex [Lig(iPr)(iso)Ni] (1b), bearing the iso-PyrrMeBox (bis(oxazolinylmethylidene)pyrrolidinido) pincer ligand, and its CO adduct [Lig(iPr)(iso)Ni(CO)] (2b) as well as to provide insight into the me...

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Detalles Bibliográficos
Autores principales: Rettenmeier, Christoph A., Wadepohl, Hubert, Gade, Lutz H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007179/
https://www.ncbi.nlm.nih.gov/pubmed/29997845
http://dx.doi.org/10.1039/c5sc04644k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007179/
https://www.ncbi.nlm.nih.gov/pubmed/29997845
http://dx.doi.org/10.1039/c5sc04644k

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