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Electronic structure and reactivity of nickel(i) pincer complexes: their aerobic transformation to peroxo species and site selective C–H oxygenation

The study is aimed at a deeper understanding of the electronic structure of the T-shaped nickel(i) complex [Lig(iPr)(iso)Ni] (1b), bearing the iso-PyrrMeBox (bis(oxazolinylmethylidene)pyrrolidinido) pincer ligand, and its CO adduct [Lig(iPr)(iso)Ni(CO)] (2b) as well as to provide insight into the me...

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Detalles Bibliográficos
Autores principales:	Rettenmeier, Christoph A., Wadepohl, Hubert, Gade, Lutz H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007179/ https://www.ncbi.nlm.nih.gov/pubmed/29997845 http://dx.doi.org/10.1039/c5sc04644k

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