Stereo- and Regiocontrolled Methylboration of Terminal Alkynes

[Image: see text] A scalable and operationally simple synthesis of trisubstituted alkenyl boronic esters has been achieved using a Zr-catalyzed carboalumination of terminal alkynes followed by in situ transmetalation with i-PrOBpin. The products are formed in good yields and with excellent regiosele...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhurakovskyi, Oleksandr, Dias, Rafael M. P., Noble, Adam, Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007961/
https://www.ncbi.nlm.nih.gov/pubmed/29741904
http://dx.doi.org/10.1021/acs.orglett.8b01252

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007961/
https://www.ncbi.nlm.nih.gov/pubmed/29741904
http://dx.doi.org/10.1021/acs.orglett.8b01252

Ejemplares similares