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Stereo- and Regiocontrolled Methylboration of Terminal Alkynes

[Image: see text] A scalable and operationally simple synthesis of trisubstituted alkenyl boronic esters has been achieved using a Zr-catalyzed carboalumination of terminal alkynes followed by in situ transmetalation with i-PrOBpin. The products are formed in good yields and with excellent regiosele...

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Detalles Bibliográficos
Autores principales:	Zhurakovskyi, Oleksandr, Dias, Rafael M. P., Noble, Adam, Aggarwal, Varinder K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007961/ https://www.ncbi.nlm.nih.gov/pubmed/29741904 http://dx.doi.org/10.1021/acs.orglett.8b01252

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