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[Ni(III)(OMe)]-mediated reductive activation of CO(2) affording a Ni(κ(1)-OCO) complex

Carbon dioxide is expected to be employed as an inexpensive and potential feedstock of C(1) sources for the mass production of valuable chemicals and fuel. Versatile chemical transformations of CO(2), i.e. insertion of CO(2) producing bicarbonate/acetate/formate, cleavage of CO(2) yielding μ-CO/μ-ox...

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Detalles Bibliográficos
Autores principales: Chiou, Tzung-Wen, Tseng, Yen-Ming, Lu, Tsai-Te, Weng, Tsu-Chien, Sokaras, Dimosthenes, Ho, Wei-Chieh, Kuo, Ting-Shen, Jang, Ling-Yun, Lee, Jyh-Fu, Liaw, Wen-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6008733/
https://www.ncbi.nlm.nih.gov/pubmed/30008996
http://dx.doi.org/10.1039/c5sc04652a