A selective removal of the secondary hydroxy group from ortho-dithioacetal-substituted diarylmethanols

We present a successful deoxygenation reaction of ortho-1,3-dithianylaryl(aryl)methanols which enables a selective removal of the secondary hydroxy group in presence of the 1,3-dithianyl moiety under reductive conditions. This reaction proceeds well with ZnI(2)/Na(CN)BH(3) in dichloroethane or benze...

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Detalles Bibliográficos
Autores principales: Czarnecka, Anna, Kowalska, Emilia, Bodzioch, Agnieszka, Skalik, Joanna, Koprowski, Marek, Owsianik, Krzysztof, Bałczewski, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009171/
https://www.ncbi.nlm.nih.gov/pubmed/29977391
http://dx.doi.org/10.3762/bjoc.14.105

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009171/
https://www.ncbi.nlm.nih.gov/pubmed/29977391
http://dx.doi.org/10.3762/bjoc.14.105

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