Selective carboxylation of reactive benzylic C–H bonds by a hypervalent iodine(III)/inorganic bromide oxidation system

An oxidation system comprising phenyliodine(III) diacetate (PIDA) and iodosobenzene with inorganic bromide, i.e., sodium bromide, in an organic solvent led to the direct introduction of carboxylic acids into benzylic C–H bonds under mild conditions. The unique radical species, generated by the homol...

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Detalles Bibliográficos
Autores principales: Dohi, Toshifumi, Ueda, Shohei, Iwasaki, Kosuke, Tsunoda, Yusuke, Morimoto, Koji, Kita, Yasuyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009330/
https://www.ncbi.nlm.nih.gov/pubmed/29977380
http://dx.doi.org/10.3762/bjoc.14.94

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009330/
https://www.ncbi.nlm.nih.gov/pubmed/29977380
http://dx.doi.org/10.3762/bjoc.14.94

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