Single and double activation of acetone by isolobal B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds

B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds induce C–H activation of acetone to yield a (2-propenyloxy)aminoborane and an unsymmetrical 1-(2-propenyloxy)-2-hydrodiborene, respectively. DFT calculations showed that, despite their stark electronic differences,...

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Detalles Bibliográficos
Autores principales: Böhnke, Julian, Brückner, Tobias, Hermann, Alexander, González-Belman, Oscar F., Arrowsmith, Merle, Jiménez-Halla, J. Oscar C., Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009441/
https://www.ncbi.nlm.nih.gov/pubmed/30009006
http://dx.doi.org/10.1039/c8sc01249k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009441/
https://www.ncbi.nlm.nih.gov/pubmed/30009006
http://dx.doi.org/10.1039/c8sc01249k

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