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Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – electron crystallography as an important tool for structure elucidation

The Ni-metallated porphyrin-based tetraphosphonic acid (Ni-tetra(4-phosphonophenyl)porphyrin, Ni-H(8)TPPP) was used for the synthesis of highly porous metal phosphonates containing the tetravalent cations Zr(4+) and Hf(4+). The compounds were thoroughly characterized regarding their sorption propert...

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Detalles Bibliográficos
Autores principales: Rhauderwiek, Timo, Zhao, Haishuang, Hirschle, Patrick, Döblinger, Markus, Bueken, Bart, Reinsch, Helge, De Vos, Dirk, Wuttke, Stefan, Kolb, Ute, Stock, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009505/
https://www.ncbi.nlm.nih.gov/pubmed/30009015
http://dx.doi.org/10.1039/c8sc01533c