Annulation cascade of arylnitriles with alkynes to stable delocalized PAH carbocations via intramolecular rhodium migration

Herein, we propose the conception of heteroatom-promoted delocalization of the positive charge of an oxonium ion and thus develop a highly efficient rhodium(iii)-catalyzed hydration and three fold C–H activation/annulation cascade of arylnitriles with alkynes, affording a structurally diverse family...

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Detalles Bibliográficos
Autores principales: Yin, Jiangliang, Zhou, Fulin, Zhu, Lei, Yang, Mufan, Lan, Yu, You, Jingsong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009538/
https://www.ncbi.nlm.nih.gov/pubmed/30009016
http://dx.doi.org/10.1039/c8sc01963k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009538/
https://www.ncbi.nlm.nih.gov/pubmed/30009016
http://dx.doi.org/10.1039/c8sc01963k

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