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Quaternary Stereocenters via an Enantioconvergent Catalytic S(N)1 Reaction
The unimolecular nucleophilic substitution (S(N)1) mechanism figures prominently in every introductory organic chemistry course. In principle, stepwise displacement of a leaving group by a nucleophile via a carbocationic intermediate allows for the construction of highly congested carbon centers. Ho...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009832/ https://www.ncbi.nlm.nih.gov/pubmed/29695848 http://dx.doi.org/10.1038/s41586-018-0042-1 |