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Quaternary Stereocenters via an Enantioconvergent Catalytic S(N)1 Reaction

The unimolecular nucleophilic substitution (S(N)1) mechanism figures prominently in every introductory organic chemistry course. In principle, stepwise displacement of a leaving group by a nucleophile via a carbocationic intermediate allows for the construction of highly congested carbon centers. Ho...

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Detalles Bibliográficos
Autores principales:	Wendlandt, Alison E., Vangal, Prithvi, Jacobsen, Eric N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009832/ https://www.ncbi.nlm.nih.gov/pubmed/29695848 http://dx.doi.org/10.1038/s41586-018-0042-1

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