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Abrupt increase in hydrogen diffusion on transition-metal surfaces during hydrogenation catalysis

A sharp increase in the rate of hydrogen isotope scrambling was identified during the hydrogenation of olefins with H(2) + D(2) mixtures on Pt(111) catalysts, which spectroscopic data suggest is due to a sudden increase in atomic hydrogen surface mobility because of a decrease in the size of the isl...

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Detalles Bibliográficos
Autores principales: Simonovis, Juan, Zaera, Francisco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013773/
https://www.ncbi.nlm.nih.gov/pubmed/30155114
http://dx.doi.org/10.1039/c6sc01249c