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Abrupt increase in hydrogen diffusion on transition-metal surfaces during hydrogenation catalysis
A sharp increase in the rate of hydrogen isotope scrambling was identified during the hydrogenation of olefins with H(2) + D(2) mixtures on Pt(111) catalysts, which spectroscopic data suggest is due to a sudden increase in atomic hydrogen surface mobility because of a decrease in the size of the isl...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013773/ https://www.ncbi.nlm.nih.gov/pubmed/30155114 http://dx.doi.org/10.1039/c6sc01249c |