Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular cross-aldol reactions

Catalytic discrimination between inequivalent formyl groups was achieved using an aniline-type acid–base catalyst for the regio-, diastereo-, and enantioselective intramolecular cross-aldol reactions of enolizable dials. Although l-proline gave a mixture of the regio- and stereoisomeric products in...

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Detalles Bibliográficos
Autores principales: Baba, Tomonori, Yamamoto, Junya, Hayashi, Kazuhiro, Sato, Makoto, Yamanaka, Masahiro, Kawabata, Takeo, Furuta, Takumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013812/
https://www.ncbi.nlm.nih.gov/pubmed/30155021
http://dx.doi.org/10.1039/c5sc04594k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013812/
https://www.ncbi.nlm.nih.gov/pubmed/30155021
http://dx.doi.org/10.1039/c5sc04594k

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