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Catalytic discrimination between formyl groups in regio- and stereoselective intramolecular cross-aldol reactions
Catalytic discrimination between inequivalent formyl groups was achieved using an aniline-type acid–base catalyst for the regio-, diastereo-, and enantioselective intramolecular cross-aldol reactions of enolizable dials. Although l-proline gave a mixture of the regio- and stereoisomeric products in...
Autores principales: | Baba, Tomonori, Yamamoto, Junya, Hayashi, Kazuhiro, Sato, Makoto, Yamanaka, Masahiro, Kawabata, Takeo, Furuta, Takumi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013812/ https://www.ncbi.nlm.nih.gov/pubmed/30155021 http://dx.doi.org/10.1039/c5sc04594k |
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