Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage

An enantioselective [3 + 2] annulation of donor–acceptor aziridines with aldehydes has been realized using a Nd(OTf)(3)/N,N′-dioxide/LiNTf(2) catalyst system, providing various chiral cis-1,3-oxazolidines in moderate to good yields with high levels of stereocontrol. A relay catalytic process is prop...

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Detalles Bibliográficos
Autores principales: Liao, Yuting, Liu, Xiaohua, Zhang, Yu, Xu, Yali, Xia, Yong, Lin, Lili, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013814/
https://www.ncbi.nlm.nih.gov/pubmed/30155018
http://dx.doi.org/10.1039/c5sc04151a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013814/
https://www.ncbi.nlm.nih.gov/pubmed/30155018
http://dx.doi.org/10.1039/c5sc04151a

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