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Assembly of inorganic [Mo(2)S(2)O(2)](2+) panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters

We describe how supramolecular assembly, mediated by control of the ratio of the hetero-atoms in the units [Mo(2)S(2)O(2)](2+) and SeO(3)(2–) leads to the formation of new types of building blocks, [(Mo(2)O(2)S(2))(3)(OH)(4)(H(2)O)(6)(SeO(3))] = {Mo(6)} and [(Mo(2)O(2)S(2))(2)(OH)(2)(H(2)O)(4)(SeO(3...

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Detalles Bibliográficos
Autores principales: Zang, Hong-Ying, Chen, Jia-Jia, Long, De-Liang, Cronin, Leroy, Miras, Haralampos N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013829/
https://www.ncbi.nlm.nih.gov/pubmed/30155022
http://dx.doi.org/10.1039/c5sc04944j