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Assembly of inorganic [Mo(2)S(2)O(2)](2+) panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters
We describe how supramolecular assembly, mediated by control of the ratio of the hetero-atoms in the units [Mo(2)S(2)O(2)](2+) and SeO(3)(2–) leads to the formation of new types of building blocks, [(Mo(2)O(2)S(2))(3)(OH)(4)(H(2)O)(6)(SeO(3))] = {Mo(6)} and [(Mo(2)O(2)S(2))(2)(OH)(2)(H(2)O)(4)(SeO(3...
Autores principales: | Zang, Hong-Ying, Chen, Jia-Jia, Long, De-Liang, Cronin, Leroy, Miras, Haralampos N. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013829/ https://www.ncbi.nlm.nih.gov/pubmed/30155022 http://dx.doi.org/10.1039/c5sc04944j |
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