Cation-mediated optical resolution and anticancer activity of chiral polyoxometalates built from entirely achiral building blocks

We report the crystallization of homochiral polyoxometalate (POM) macroanions {CoSb(6)O(4)(H(2)O)(3)[Co(hmta)SbW(8)O(31)](3)}(15–) (1, hmta = hexamethylenetetramine) via the counter cation-mediated chiral symmetry breaking and asymmetric autocatalytic processes. In the presence of low Co(2+) concent...

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Detalles Bibliográficos
Autores principales: Zhang, Zhi-Ming, Duan, Xiaopin, Yao, Shuang, Wang, Zhishu, Lin, Zekai, Li, Yang-Guang, Long, La-Sheng, Wang, En-Bo, Lin, Wenbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013930/
https://www.ncbi.nlm.nih.gov/pubmed/30155068
http://dx.doi.org/10.1039/c5sc04408a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013930/
https://www.ncbi.nlm.nih.gov/pubmed/30155068
http://dx.doi.org/10.1039/c5sc04408a

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