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Structural switching in self-assembled metal–ligand helicate complexes via ligand-centered reactions

Ligand centered reactions are capable of conferring structural switching between a metastable, self-assembled Fe–iminopyridine aggregate and a stable M(2)L(3) helicate. The reactivity is directed and accelerated by the stability of the final product structure. Under aerobic conditions, both substitu...

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Detalles Bibliográficos
Autores principales: Holloway, Lauren R., McGarraugh, Hannah H., Young, Michael C., Sontising, Watit, Beran, Gregory J. O., Hooley, Richard J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014161/
https://www.ncbi.nlm.nih.gov/pubmed/30155089
http://dx.doi.org/10.1039/c6sc01038e