Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes

Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures...

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Detalles Bibliográficos
Autores principales: Cui, Peng, Hoffbauer, Melissa R., Vyushkova, Mariya, Iluc, Vlad M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014298/
https://www.ncbi.nlm.nih.gov/pubmed/30155092
http://dx.doi.org/10.1039/c6sc00948d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014298/
https://www.ncbi.nlm.nih.gov/pubmed/30155092
http://dx.doi.org/10.1039/c6sc00948d

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