Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes

Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Peng, Hoffbauer, Melissa R., Vyushkova, Mariya, Iluc, Vlad M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014298/
https://www.ncbi.nlm.nih.gov/pubmed/30155092
http://dx.doi.org/10.1039/c6sc00948d
_version_ 1783334208206274560
author Cui, Peng
Hoffbauer, Melissa R.
Vyushkova, Mariya
Iluc, Vlad M.
author_facet Cui, Peng
Hoffbauer, Melissa R.
Vyushkova, Mariya
Iluc, Vlad M.
author_sort Cui, Peng
collection PubMed
description Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that can be interrupted in the presence of a donor solvent.
format Online
Article
Text
id pubmed-6014298
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-60142982018-08-28 Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes Cui, Peng Hoffbauer, Melissa R. Vyushkova, Mariya Iluc, Vlad M. Chem Sci Chemistry Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that can be interrupted in the presence of a donor solvent. Royal Society of Chemistry 2016-07-01 2016-03-24 /pmc/articles/PMC6014298/ /pubmed/30155092 http://dx.doi.org/10.1039/c6sc00948d Text en This journal is © The Royal Society of Chemistry 2016 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Cui, Peng
Hoffbauer, Melissa R.
Vyushkova, Mariya
Iluc, Vlad M.
Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title_full Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title_fullStr Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title_full_unstemmed Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title_short Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
title_sort heterobimetallic pd–k carbene complexes via one-electron reductions of palladium radical carbenes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014298/
https://www.ncbi.nlm.nih.gov/pubmed/30155092
http://dx.doi.org/10.1039/c6sc00948d
work_keys_str_mv AT cuipeng heterobimetallicpdkcarbenecomplexesviaoneelectronreductionsofpalladiumradicalcarbenes
AT hoffbauermelissar heterobimetallicpdkcarbenecomplexesviaoneelectronreductionsofpalladiumradicalcarbenes
AT vyushkovamariya heterobimetallicpdkcarbenecomplexesviaoneelectronreductionsofpalladiumradicalcarbenes
AT ilucvladm heterobimetallicpdkcarbenecomplexesviaoneelectronreductionsofpalladiumradicalcarbenes

Ejemplares similares