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Heterobimetallic Pd–K carbene complexes via one-electron reductions of palladium radical carbenes
Heterobimetallic Pd–K carbenes featuring Pd–C(carbene)–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp(2))P}(tBu)PdI] ([PC(sp(2))P](tBu) = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014298/ https://www.ncbi.nlm.nih.gov/pubmed/30155092 http://dx.doi.org/10.1039/c6sc00948d |