Formal enantioconvergent substitution of alkyl halides via catalytic asymmetric photoredox radical coupling

Classic nucleophilic substitution reactions (S(N)1 and S(N)2) are not generally amenable to the enantioselective variants that use simple and racemic alkyl halide electrophiles. The merging of transition metal catalysis and radical chemistry with organometallic nucleophiles is a versatile method for...

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Detalles Bibliográficos
Autores principales: Li, Jiangtao, Kong, Manman, Qiao, Baokun, Lee, Richmond, Zhao, Xiaowei, Jiang, Zhiyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6015005/
https://www.ncbi.nlm.nih.gov/pubmed/29934495
http://dx.doi.org/10.1038/s41467-018-04885-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6015005/
https://www.ncbi.nlm.nih.gov/pubmed/29934495
http://dx.doi.org/10.1038/s41467-018-04885-3

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