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Formal enantioconvergent substitution of alkyl halides via catalytic asymmetric photoredox radical coupling
Classic nucleophilic substitution reactions (S(N)1 and S(N)2) are not generally amenable to the enantioselective variants that use simple and racemic alkyl halide electrophiles. The merging of transition metal catalysis and radical chemistry with organometallic nucleophiles is a versatile method for...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6015005/ https://www.ncbi.nlm.nih.gov/pubmed/29934495 http://dx.doi.org/10.1038/s41467-018-04885-3 |