A supramolecularly tunable chiral diphosphine ligand: application to Rh and Ir-catalyzed enantioselective hydrogenation

A supramolecularly tunable chiral bisphosphine ligand bearing two pyridyl-containing crown ethers, (–) or (+)-Xyl-P16C6-Phos, was fabricated and utilized in the Rh-catalyzed asymmetric hydrogenation of α-dehydroamino acid esters and Ir-catalyzed asymmetric hydrogenation of quinolines in high yields...

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Detalles Bibliográficos
Autores principales: Zhang, Xi-Chang, Hu, Yi-Hu, Chen, Chuan-Fu, Fang, Qiang, Yang, Li-Yao, Lu, Ying-Bo, Xie, Lin-Jie, Wu, Jing, Li, Shijun, Fang, Wenjun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6016442/
https://www.ncbi.nlm.nih.gov/pubmed/30155106
http://dx.doi.org/10.1039/c6sc00589f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6016442/
https://www.ncbi.nlm.nih.gov/pubmed/30155106
http://dx.doi.org/10.1039/c6sc00589f

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