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Methane activation by gold-doped titanium oxide cluster anions with closed-shell electronic structures
The reactivity of closed-shell gas phase cluster anions AuTi(3)O(7)(–) and AuTi(3)O(8)(–) with methane under thermal collision conditions was studied by mass spectrometric experiments and quantum chemical calculations. Methane activation was observed with the formation of AuCH(3) in both cases, whil...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6016522/ https://www.ncbi.nlm.nih.gov/pubmed/30155123 http://dx.doi.org/10.1039/c6sc00539j |