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Observation of the influence of dipolar and spin frustration effects on the magnetocaloric properties of a trigonal prismatic {Gd(7)} molecular nanomagnet
We report the synthesis and structure of a molecular {Gd(7)} cage of the formula ((i)Pr(2)NH(2))(6)[Gd(7)(μ(3)-OH)(3)(CO(3))(6)(O(2)C(t)Bu)(12)] which has crystallographic C(3h) symmetry. Low temperature specific heat and adiabatic demagnetization experiments (the latter achieving temperatures below...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6016719/ https://www.ncbi.nlm.nih.gov/pubmed/30155137 http://dx.doi.org/10.1039/c6sc01415a |