Cargando…

Observation of the influence of dipolar and spin frustration effects on the magnetocaloric properties of a trigonal prismatic {Gd(7)} molecular nanomagnet

We report the synthesis and structure of a molecular {Gd(7)} cage of the formula ((i)Pr(2)NH(2))(6)[Gd(7)(μ(3)-OH)(3)(CO(3))(6)(O(2)C(t)Bu)(12)] which has crystallographic C(3h) symmetry. Low temperature specific heat and adiabatic demagnetization experiments (the latter achieving temperatures below...

Descripción completa

Detalles Bibliográficos
Autores principales:	Pineda, Eufemio Moreno, Lorusso, Giulia, Zangana, Karzan H., Palacios, Elias, Schnack, Jürgen, Evangelisti, Marco, Winpenny, Richard E. P., McInnes, Eric J. L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6016719/ https://www.ncbi.nlm.nih.gov/pubmed/30155137 http://dx.doi.org/10.1039/c6sc01415a

Ejemplares similares

Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements
por: Sharples, Joseph W., et al.
Publicado: (2014)

Modelling the structural disorder in trigonal-prismatic coordinated transition metal dichalcogenides
por: Ursi, Federica, et al.
Publicado: (2023)

A {Gd(12)Na(6)} Molecular Quadruple-Wheel with a Record Magnetocaloric Effect at Low Magnetic Fields and Temperatures
por: Tziotzi, Thomais G., et al.
Publicado: (2023)

[MIII2MII3](n+) trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands
por: Sanz, S., et al.
Publicado: (2017)

Trends in trigonal prismatic Ln-[1]ferrocenophane complexes and discovery of a Ho(3+) single-molecule magnet
por: Latendresse, Trevor P., et al.
Publicado: (2020)

Magnetic frustration induced large magnetocaloric effect in the absence of long range magnetic order
por: Pakhira, Santanu, et al.
Publicado: (2017)

Chirality and Magnetocaloricity in GdFeTeO(6) as Compared to GdGaTeO(6)
por: Zvereva, Elena, et al.
Publicado: (2021)

Free-Spin Dominated Magnetocaloric Effect in Dense Gd(3+) Double Perovskites
por: Koskelo, EliseAnne C., et al.
Publicado: (2022)

Nanoscale control of competing interactions and geometrical frustration in a dipolar trident lattice
por: Farhan, Alan, et al.
Publicado: (2017)

Molecular nanomagnets with switchable coupling for quantum simulation
por: Chiesa, Alessandro, et al.
Publicado: (2014)

Tunable Magnetocaloric Properties of Gd-Based Alloys by Adding Tb and Doping Fe Elements
por: Xu, Lingfeng, et al.
Publicado: (2019)

Trigonal Prismatic Coordination of Discrete Rare Earth Ions, Enforced by the Polyoxotungstate [P(4)W(27)O(99)(H(2)O)](16–)
por: Iftikhar, Tuba, et al.
Publicado: (2021)

Rotating magnetocaloric effect and unusual magnetic features in metallic strongly anisotropic geometrically frustrated TmB(4)
por: Orendáč, Matúš, et al.
Publicado: (2018)

Magnetic and Magnetocaloric Properties of the A(2)LnSbO(6) Lanthanide Oxides on the Frustrated fcc Lattice
por: Koskelo, EliseAnne C., et al.
Publicado: (2023)

Magnetic Behavior of Trigonal (Bi-)pyramidal 3d(8) Mononuclear Nanomagnets: The Case of [Ni(MDABCO)(2)Cl(3)]ClO(4)
por: Georgiev, Miroslav, et al.
Publicado: (2023)

Author Correction: Nanoscale control of competing interactions and geometrical frustration in a dipolar trident lattice
por: Farhan, Alan, et al.
Publicado: (2017)

Nanomagnetism and spintronics
por: Shinjo, Teruya
Publicado: (2014)

Principles of Nanomagnetism
por: Guimaraes, Alberto P
Publicado: (2009)

Molecular nanomagnets
por: Gatteschi, Dante, et al.
Publicado: (2006)

Handbook of Nanomagnetism
por: Lukaszew, Rosa
Publicado: (2015)

Gd(III)–Gd(III) Relaxation-Induced Dipolar Modulation Enhancement for In-Cell Electron Paramagnetic Resonance Distance Determination
por: Azarkh, Mykhailo, et al.
Publicado: (2019)

Crystal structure of diethyl 2,2′-[((1E,1′E)-{[(1R,4R)-cyclohexane-1,4-diyl]bis(azanylylidene)}bis(methanylylidene))bis(1H-pyrrole-2,1-diyl)]diacetate
por: Alshawi, Jasim, et al.
Publicado: (2015)

Giant Anisotropic Magnetocaloric Effect in Double-perovskite Gd(2)CoMnO(6) Single Crystals
por: Moon, J. Y., et al.
Publicado: (2017)

Structural, magnetic, and magnetocaloric properties of R(2)NiMnO(6) (R = Eu, Gd, Tb)
por: Shinde, K. P., et al.
Publicado: (2021)

Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts
por: Wang, Meng, et al.
Publicado: (2023)

Nanomagnetism: applications and perspectives
por: Fermon, Claude, et al.
Publicado: (2016)

Three-dimensional nanomagnetism
por: Fernández-Pacheco, Amalio, et al.
Publicado: (2017)

Effect of Co, Ti and Cr Additions on Microstructure, Magnetic Properties and Corrosion Resistance of Magnetocaloric Gd-Ge-Si Alloys
por: Hasiak, Mariusz, et al.
Publicado: (2020)

The Prismatic Effect on Stereoacuity in Intermittent Exotropia
por: Choi, Kyoung Sub, et al.
Publicado: (2010)

Limited Plasticity of Prismatic Visuomotor Adaptation
por: Spang, Karoline, et al.
Publicado: (2017)

The Cure of Squinting by the Use of Prismatic Spectacles
por: Wells, T. Spencer
Publicado: (1853)

Nanomagnet-facilitated pharmaco-compatibility for cancer diagnostics: Underlying risks and the emergence of ultrasmall nanomagnets
por: Parimi, Divya S., et al.
Publicado: (2022)

Molecular nanomagnets and related phenomena
por: Gao, Song
Publicado: (2015)

Artificial multilayers and nanomagnetic materials
por: SHINJO, Teruya
Publicado: (2013)

Increasing the Modulation Depth of Gd(III)-Based Pulsed Dipolar EPR Spectroscopy (PDS) with Porphyrin–Gd(III) Laser-Induced Magnetic Dipole Spectroscopy
por: Scherer, Andreas, et al.
Publicado: (2022)

[U(III){N(SiMe(2)tBu)(2)}(3)]: A Structurally Authenticated Trigonal Planar Actinide Complex
por: Goodwin, Conrad AP, et al.
Publicado: (2014)

Nanomagnets: Growth of Co Nanomagnet Arrays with Enhanced Magnetic Anisotropy (Adv. Sci. 9/2016)
por: Fernández, Laura, et al.
Publicado: (2016)

Dataset on comparable magnetocaloric properties of melt-extracted Gd(36)Tb(20)Co(20)Al(24) metallic glass microwires
por: Yin, Hangboce, et al.
Publicado: (2019)

Structure, Magnetocaloric Effect and Critical Behavior of the Fe(60)Co(12)Gd(4)Mo(3)B(21) Amorphous Ribbons
por: Łukiewska, Agnieszka, et al.
Publicado: (2021)

Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln(3)(adipate)(4.5)(DMF)(2) (Ln = Gd–Er) Framework Series
por: Doheny, Patrick W., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_gjfoacsaqbd801rguvslp0avu2