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Anomaly in the Chain Length Dependence of n-Alkane Diffusion in ZIF-4 Metal-Organic Frameworks

Molecular diffusion is commonly found to slow down with increasing molecular size. Deviations from this pattern occur in some host materials with pore sizes approaching the diameters of the guest molecules. A variety of theoretical models have been suggested to explain deviations from this pattern,...

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Detalles Bibliográficos
Autores principales: Hwang, Seungtaik, Gopalan, Arun, Hovestadt, Maximilian, Piepenbreier, Frank, Chmelik, Christian, Hartmann, Martin, Snurr, Randall Q., Kärger, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017190/
https://www.ncbi.nlm.nih.gov/pubmed/29543777
http://dx.doi.org/10.3390/molecules23030668