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Vinylation of a Secondary Amine Core with Calcium Carbide for Efficient Post-Modification and Access to Polymeric Materials

We developed a simple and efficient strategy to access N-vinyl secondary amines of various naturally occurring materials using readily available solid acetylene reagents (calcium carbide, KF, and KOH). Pyrrole, pyrazole, indoles, carbazoles, and diarylamines were successfully vinylated in good yield...

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Detalles Bibliográficos
Autores principales: Rodygin, Konstantin S., Bogachenkov, Alexander S., Ananikov, Valentine P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017323/
https://www.ncbi.nlm.nih.gov/pubmed/29534039
http://dx.doi.org/10.3390/molecules23030648