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Pd-Catalyzed, Highly Selective C(sp(2))-Br Bond Coupling Reactions of o-(or m-, or p-) Chloromethyl Bromobenzene with Arylboronic Acids

Highly selective C(sp(2))–C(sp(2)) cross-coupling of dihalogenated hydrocarbons comprising C(sp(2))–Br and C(sp(3))–Cl bonds with arylboronic acids is reported. This highly selective coupling reaction of the C(sp(2))–Br bond is successfully achieved using Pd(OAc)(2) and PCy(3)·HBF(4) as the palladiu...

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Detalles Bibliográficos
Autores principales: Pei, Ming-ming, Liu, Ping, Liu, Yan, Lv, Xin-ming, Ma, Xiao-wei, Dai, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017369/
https://www.ncbi.nlm.nih.gov/pubmed/29462874
http://dx.doi.org/10.3390/molecules23020433