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Visible light amination/Smiles cascade: access to phthalazine derivatives

We report the synthesis of various phthalazines via a new cascade reaction, initiated by visible light photocatalysis, involving a radical hydroamination reaction followed by a radical Smiles rearrangement. Phthalazine derivatives are obtained in high yields and from a broad scope readily accessible...

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Detalles Bibliográficos
Autores principales: Brachet, Etienne, Marzo, Leyre, Selkti, Mohamed, König, Burkhard, Belmont, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6018559/
https://www.ncbi.nlm.nih.gov/pubmed/30155150
http://dx.doi.org/10.1039/c6sc01095d