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Aerobic alcohol oxidation and oxygen atom transfer reactions catalyzed by a nonheme iron(ii)–α-keto acid complex
α-Ketoglutarate-dependent enzymes catalyze many important biological oxidation/oxygenation reactions. Iron(iv)–oxo intermediates have been established as key oxidants in these oxidation reactions. While most reported model iron(ii)–α-keto acid complexes exhibit stoichiometric reactivity, selective o...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020522/ https://www.ncbi.nlm.nih.gov/pubmed/30155184 http://dx.doi.org/10.1039/c6sc01476c |