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ortho-Selective C–H addition of N,N-dimethyl anilines to alkenes by a yttrium catalyst

The efficient and selective ortho-alkylation of N,N-dimethyl anilines via C–H addition to alkenes was achieved for the first time using a cationic half-sandwich yttrium catalyst. This protocol constitutes a straightforward and atom-economical route for the synthesis of a new family of tertiary anili...

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Detalles Bibliográficos
Autores principales: Song, Guoyong, Luo, Gen, Oyamada, Juzo, Luo, Yi, Hou, Zhaomin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020524/
https://www.ncbi.nlm.nih.gov/pubmed/30155176
http://dx.doi.org/10.1039/c6sc00833j